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Unshared electron pair

An unshared electron pair, also known as a nonbonding pair of electrons or as a lone pair of electrons, is two electrons in the same orbital in the outer shell of an atom that are not used in the formation of a covalent bond.

Ammonia (NH3) is an example of a molecule with one unshared electron pair.

It is necessary to examine the unshared electron pairs when determining the electron pair geometry and subsequently the molecular shape of a covalent compound.

Molecular model of ammonia
Structural formula of ammonia

Molecular model of ammonia
An arrow points to the unshared
electron pair.
Structural formula of ammonia - NH3
The unshared electron pair is represented by red dots.






Created and maintained by: Dr. Anna Cavinato anna.cavinato@eou.edu and Dr. David Camp
All Material Copyright Eastern ChemWeb, Eastern Oregon University, 2003.